我的理解,刚发图乱了,重发一下,五线谱更好 :)


所有跟贴·加跟贴·新语丝读书论坛

送交者: blobfish 于 2009-06-11, 19:23:10:

回答: 008, 你说的这个算法我知道。但是我比较笨,想不出来,你要是能给画4个图 由 qfly 于 2009-06-11, 10:45:13:

三个原子在一起,先不要管它们是不是排成一条线. 把HCN看成三角形.
------C----
-----/-\---
----/---\--
---H-----O-

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Vibration Mode--1: H---C vibration.
------C----
-----/-\---
----/---\--
---/-----O-
--H
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Vibration Mode--2: C---O vibration.
------C----
-----/-\---
----/---\--
---H-----\-
----------O


~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Vibration Mode--3: H---O vibration, or called bending
------C----
-----/-\---
----/---\--
---H->-<-O-

in which H and O atoms will move toward or away to each other.

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
Vibration Mode--4: off-plane vibration.
The equilibrium position of C atom, H and O will keep in the same plane. only C atom vibrates up and down from this triangle plane.

-------^-----
-------C-----
-----/-|-\---
----/--V--\--
---H-------O-

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
-----
Finally, I think the linear structure is very misleading. Triangle could simplified the problem.
best regards.




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